Chemistry · applications · one sitting

The Working Bench

Every box below is shut until you open it. Open one, ask the question out loud, let them guess, then reveal. The formulas are live: put real numbers in the fields and the page shows the whole chain, not just an answer.

Modelled on Ball, Introductory Chemistry — ch. 2–6, 11, 12

Part 0 · The Ramp

Ten questions that get harder. It is not a test and nothing is graded — it tells you, in about eight minutes, which rung the room is actually standing on, so you know where today's lesson has to start.

Furthest rung cleared: none yet · answered 0 of 10
The ten rungsask · guess · reveal

Part 1 · The Framework

Ball makes one decision early in the book that is worth stealing whole: every quantitative problem in chemistry is worked as one of two kinds, and never as a trick. His reason is the right one — a student who uses a shortcut and gets a wrong answer has no idea where it broke.

The two kinds of problemsay this before anything else

Objective

Given any problem in this course, name which of the two it is before writing a single number.

1 · The conversion-factor problem

You have a quantity. You want the same stuff expressed in a different unit. Multiply by fractions that equal 1, arranged so the unit you don't want cancels.

123.2 g Cl₂ × ──1 mol Cl₂── = 1.738 mol Cl₂ 70.90 g Cl₂

Read it aloud as: grams of chlorine, times one mole per 70.90 grams, gives moles. The grams cancel because one is upstairs and one is downstairs. That sentence is the method.

2 · The formula problem

A relationship is already written down — PV = nRT, M = mol/L, pH = −log[H₃O⁺]. Identify the unknown, rearrange, substitute with units attached.

The road map

Almost every reaction problem is the same three moves, and the middle one is the only place the balanced equation is allowed in:
mass A → mol A → mol B → mass B
Chemical equations are not balanced in grams. They are balanced in moles. So you must arrive in moles before you cross the arrow, and convert back after.

The four checks, every time

#CheckWhat goes wrong without it
1Is the equation balanced?Your mole ratio is fiction.
2Did you convert to moles before the arrow?You multiplied grams by a mole ratio. Nothing means anything after that.
3Do the units cancel to what you were asked for?You have a number with the wrong unit, which is a wrong answer.
4Sig figs — how precise was the worst measurement?You report six digits of confidence you never had.

Part 2 · The Bench

Eight applications. Each box holds the situation, the formula, a worked example, a faded one where they finish the last step themselves, and a live solver. Work them in order or pull the one you need.

A · Molar massthe gateway · every other box needs it
Where it shows up: a label says 500 mg of calcium carbonate. Your body does not care about milligrams; it reacts in particles. Molar mass is the bridge between the scale in your hand and the particles doing the work.

Objective

From a chemical formula, calculate the mass of one mole of it.

Add up the atomic mass of every atom in the formula. A subscript multiplies what it follows; a subscript after a parenthesis multiplies everything inside it.

Ca(NO₃)₂ → Ca 1 × 40.078 = 40.078 N 2 × 14.007 = 28.014 O 6 × 15.999 = 95.994 ─────── 164.09 g/mol

The trap: the 2 outside the bracket multiplies both the N and the three O's. Six oxygens, not three.

Test yourself — what is the molar mass of (NH₄)₂SO₄, ammonium sulfate? Fertilizer. Answer in g/mol.

Solver · molar mass

Enter a formula.

Write subscripts as ordinary numbers: H2O, Ca(NO3)2, Al2(SO4)3. Hydrate dots (·5H2O) are not parsed — add the water by hand.

Key takeaway

Molar mass is a conversion factor with two faces: g/mol going one way, mol/g going the other. Which face you use is decided entirely by which unit you need to cancel.
B · Mass, moles, particlescounting what you cannot see
Where it shows up: you cannot count atoms, so you weigh them — the same trick as counting rice by the kilo instead of by the grain. A mole is just a number: 6.022 × 10²³ of anything.

Objective

Move in any direction between grams, moles, and number of particles.
mass ──(÷ molar mass)──▶ moles ──(× 6.022×10²³)──▶ particles
36.0 g H₂O × ──1 mol H₂O── = 2.00 mol H₂O 18.02 g H₂O

Faded example — finish the last step. You have 2.00 mol of water. How many molecules is that?

Solver · mass ↔ moles ↔ particles

Give a formula and either a mass or a mole amount.

Fill mass or moles, not both — whichever you leave blank is what gets calculated.

Key takeaway

The mole is a count, like a dozen. Everything else in this lesson is that one idea wearing different clothes.
C · Mass to mass through a reactionthe airbag · the central skill
Where it shows up: an airbag has about 40 milliseconds to fill roughly 60 litres. It is packed with sodium azide, which decomposes to nitrogen gas: 2NaN₃ → 2Na + 3N₂. Put in too little and the bag is soft; too much and it hits like a wall. The mass is not a guess — it is this calculation.

Objective

From a given mass of one substance, calculate the mass of another substance in the same reaction.
mass A → mol A → (mole ratio) → mol B → mass B

Worked, in one line — 86.4 g of potassium into MgCl₂ + 2K → Mg + 2KCl:

86.4 g K × ──1 mol K── × ──1 mol Mg── × ──24.31 g Mg── = 26.87 g Mg 39.09 g K 2 mol K 1 mol Mg

Three fractions, three cancellations, one surviving unit. The middle fraction is the only one that came from the balanced equation.

Test yourself — what mass of H₂ is produced when 122 g of Zn react? Zn + 2HCl → ZnCl₂ + H₂

Solver · mass A → mass B

Balance the equation first — the coefficients are the whole point.

Loaded with the airbag: 130 g of NaN₃ in 2NaN₃ → 2Na + 3N₂.

Key takeaway

You may never take a mole ratio across grams. Convert, cross, convert back — in that order, every time.
D · Limiting reagentwhich ingredient runs out first
Where it shows up: ten slices of bread and three slices of cheese makes three sandwiches, not ten. Every industrial process on earth is this question — and the leftover reactant is money sitting in a tank.

Objective

Given amounts of two reactants, decide which one limits the reaction, and calculate how much product it can make.

The method: convert both to moles, divide each by its own coefficient, and the smaller answer is the one that runs out.

N₂ + 3H₂ → 2NH₃ given 35.0 g N₂ and 12.0 g H₂ N₂ : 35.0 g ÷ 28.01 g/mol = 1.249 mol ÷ 1 = 1.249 H₂ : 12.0 g ÷ 2.016 g/mol = 5.952 mol ÷ 3 = 1.984 ← larger, so H₂ is in excess N₂ limits. 1.249 mol N₂ × (2 mol NH₃ / 1 mol N₂) × 17.03 g/mol = 42.6 g NH₃

Predict before you calculate — you double the hydrogen to 24.0 g and leave the nitrogen at 35.0 g. Does the yield of ammonia go up?

Solver · limiting reagent & theoretical yield

Loaded with the Haber process.

Key takeaway

Divide moles by coefficient. The smallest quotient names the limiting reagent — and that reagent alone sets the yield.
E · Percent yieldaspirin · why the lab never matches the paper
Where it shows up: you synthesise aspirin in the lab, the calculation promises 3.6 g, and you weigh 2.7 g. Nothing went wrong. Product sticks to glassware, stays dissolved, reacts backwards. Percent yield is how chemistry admits the gap between arithmetic and a bench.

Objective

Calculate percent yield, and say which of the two numbers in it came from a balance and which came from a calculation.
percent yield = ──actual yield── × 100 theoretical yield = ──2.7 g── × 100 = 75 % 3.6 g

Theoretical yield is the answer from box C or D. Actual yield can only come from weighing the thing you made. A percent yield over 100 does not mean you beat chemistry — it means your product is still wet.

Test yourself — the theoretical yield of ammonia was 42.6 g. You collect 31.0 g. What is the percent yield?

Solver · percent yield

Two masses in, one percentage out.

Key takeaway

Theoretical yield is what the equation permits. Actual yield is what the balance says. The ratio is a statement about technique, not about chemistry.
F · Molarity and dilutionthe IV bag · the bleach bottle
Where it shows up: a saline drip is 0.154 M NaCl because that is the concentration of your own blood plasma. Get it wrong in either direction and red cells swell or shrivel. Concentration is not a chemistry-class abstraction; it is a dose.

Objective

Calculate molarity from mass and volume, and dilute a stock solution to a working concentration.
M = ──moles of solute── M₁V₁ = M₂V₂ litres of solution

The dilution formula is a conservation statement in disguise: adding water changes the volume and the concentration, but not the number of moles already in the flask.

Test yourself — you need 500. mL of 0.100 M HCl and you have 2.00 M stock. What volume of stock do you measure out?

Solver · molarity

Loaded with normal saline: 9.00 g NaCl per litre.

Solver · dilution (M₁V₁ = M₂V₂)

Leave exactly one field empty.

Key takeaway

Dilution moves volume and concentration in opposite directions and leaves the moles alone. That is the whole formula.
G · The ideal gas lawscuba · the airbag's volume
Where it shows up: a diver's lungs at ten metres hold air at twice the surface pressure. Come up holding your breath and that volume doubles inside your chest. Boyle's law is not an exam topic to a diver; it is a rule about staying alive.

Objective

Solve PV = nRT for any one of the four quantities, and connect it back to the mole answer from box C.
PV = nRT R = 0.08206 L·atm·mol⁻¹·K⁻¹ Temperature is ALWAYS in kelvin: K = °C + 273.15

Closing the loop on the airbag: box C says 130 g of NaN₃ gives 3.00 mol of N₂. At 25 °C and 1.00 atm that is V = nRT/P = (3.00)(0.08206)(298.15)/1.00 ≈ 73 L — the right order of magnitude for a driver's airbag, which is the point of the whole design.

Predict — a sealed rigid canister is heated from 25 °C to 50 °C. Does the pressure inside double?

Solver · PV = nRT

Leave exactly one field empty.

Enter temperature in °C — the solver converts to kelvin and shows it doing so.

Key takeaway

Four quantities, one equation, and a unit rule that is not negotiable: kelvin, litres, atmospheres, moles.
H · pHstomach acid · the logarithm that bites
Where it shows up: your stomach runs near pH 1.5 — acid strong enough to dissolve the metal in a nail. It does not dissolve you because the lining rebuilds itself every few days. An antacid does not "cancel" acid; it neutralises some of it and moves the number.

Objective

Convert between hydronium concentration and pH, and say what one pH unit is actually worth.
pH = −log[H₃O⁺] [H₃O⁺] = 10^(−pH) 0.010 M HCl → pH = −log(0.010) = 2.00

One pH unit is a factor of ten. Lemon juice at pH 2 is not "twice" as acidic as tomato juice at pH 4 — it is a hundred times.

Test yourself — a solution has [H₃O⁺] = 1.0 × 10⁻⁵ M. What is its pH?

Solver · pH ↔ [H₃O⁺]

Fill one, leave the other blank.

Key takeaway

pH is a compressed scale. Every step of 1 is a tenfold change in the thing that actually does the chemistry.

Your notes

Saved in this browser as you type. They stay on this machine — nothing is sent anywhere.

Notes from deliverysaves as you type

What the ramp revealed — where the room actually is

What landed, what didn't

For next time

Method — why the page is shaped this wayfor the record

Backward fading. Each application gives a complete worked example first, then a problem where only the last step is left to the student, then an open problem. In a study of 47 underprepared college chemistry students, 74 % preferred faded examples to open-ended problems, and that cohort finished the semester ahead of their college-ready peers on both multiple-choice and open-ended final questions. A blank problem is not harder teaching; it is less teaching.

Prediction before reveal. Two boxes here ask for a prediction that most rooms get wrong — the excess-reactant question in D and the Celsius-doubling question in G. Being wrong out loud first is what makes the correction stick. Neither is scored.

Answers one action away, never hidden. Every check reveals the reasoning, not just a verdict, because a student who cannot see where the logic broke learns nothing from being told they are wrong.

Collapsed by default. Only one thing is open at a time so the screen never becomes a wall. You control what the room sees.

Two problem types, no shortcuts. Taken from the book: consistency in problem solving beats clever tricks, because tricks fail silently.

Sources: Ball, Introductory Chemistry — ch. 5 (stoichiometry and the mole), ch. 6 (gases), ch. 11 (solutions), ch. 12 (acids and bases). Faded-example findings: Exploring the Use of Faded Worked Examples as a Problem Solving Approach for Underprepared Students, ERIC EJ1086007.

The Working Bench · built for one sitting · all solver math verified against the book's own worked answers